"That's not what happened though. The collector took the sample home, which is against the mlb policy, so that automatically makes the sample invalid. Not only did he take it home he stored the sample wrong for 48 hours, then shipped it to the lab. Going by policy the second the lab saw the dates they should of threw the sample out and requested another sample from Braun immediately."
um no it doesnt, and read the protocols, the protocols allows for this
http://hardballtalk.nbcsports.com/2012/02/23/was-there-really-a-violation-of-chain-of-custody-protocol-in-the-ryan-braun-ped-case/?utm_source=dlvr.it&utm_medium=twitter
"Braun’s argument during his January appeal in New York City was that the courier who collected his urine made a number of against-protocol moves after leaving the testing area. But were mistakes really made?
The courier did not immediately head to a FedEx Office after collecting Braun’s sample in early October because it was late on a Saturday night and he figured the store would be closed. Braun (or, rather, his lawyers) argued in January that the courier’s action was against policy, but the MLB-MLBPA joint drug agreement states that “specimens cannot be placed in a FedEx Drop Box” and the five FedEx Office locations closest to Miller Park don’t keep their doors open past 9 p.m. on Saturdays.
Also, none of the FedEx Office locations in the Milwaukee area ship items out on Sundays. So instead of handing the sealed cup of urine to a FedEx Office employee at some point Sunday and hoping for the best, the courier followed the terms of the MLB-MLBPA joint drug agreement (see pages 37-39) by storing Braun’s urine sample in a refrigerator at his residence until Monday morning, when FedEx could finally get the shipment to the appropriate testing lab in Montreal.
The MLB-MLBPA joint drug agreement fully allows for temporary storage by couriers — people who are trained and paid to handle drug test samples, and do so often — as long as the specimen can be “appropriately safeguarded,” kept in a “cool and secure location,” with “chain of custody intact.” A refrigerator in the private residence of a trained professional would seem to fit that bill."
For those who want access to the actual Chain of Custody protocol in the MLBPA's agreement with MLB, here it is: http://mlbplayers.mlb.com/pa/pdf/jda.pdf
Here's the statement on FedEx drop boxes:
"When all of the specimens have been collected at the collection site, the Collector shall take the specimens in the appropriate packaging to a FedEx Customer Service Center for shipment. The specimens cannot be placed in a FedEx Drop Box location. "
And the requirements for if the item can't be shipped right away:
" If the specimen is not immediately prepared for shipment, the Collector shall ensure that it is appropriately safeguarded during temporary storage.
1. The Collector must keep the chain of custody intact.
2. The Collector must store the samples in a cool and secure location. "